High Temperature Ferritic & Austenitic
High temperature grades - performance at 550°C and above
high-temperature stainless steels have been specifically designed for
temperatures up to 1150 °C. This has been achieved by the addition of a number of important alloying elements in the steel – ensuring superior performance across a wide spectrum of high-temperature applications.
High Temperature Austenitic Grades
High temperature austenitic steels are commonly employed in a number of applications where the temperature exceeds 550°C, for instance in equipment and components within the iron, steel and other metallurgical industries, the engineering industry, energy conversion plants and the cement industry.
An important consideration at high temperatures is that creep strength is usually the primary dimensioning factor. This means that by choosing the right material, you not only extend the lifetime of your application, but can also specify a thinner material for overall savings in cost. This applies especially to our high temperature austenitic grades 153 MA™ 253 MA™.
High Temperature Ferritic Grades
The main alloying element in the ferritic grades is chromium. Its positive effect on the scaling resistance is enhanced by silicon and aluminium.
Ferritic steel grades 4713 and 4724 are best suited for temperatures between 550°C and 850°C. The higher alloyed 4736, 4742, 4762 grades can be applied at temperatures up to 1150°C showing excellent resistance against reducing sulphur attacks and molten metals.
Due to their ferritic structure, the ferritic steels show lower strength at temperatures exceeding 600°C, but are more resistant to thermal shocks than high temperature austenitic stainless steels. With the thermal conductivity higher and the thermal expansion lower than the respective values for austenitic steels, equal thermal shocks will result in lower thermal stresses in the ferritic material. In these terms, ferrites allow greater tolerances for design and operation.
High temperature ferritic grades are mainly used in high temperature applications with sulphurous atmospheres and/or at low tensile loads such as for installations within chemical industry, power industry, metalworking industry and furnace technology.
Grades :
Austenitic high temperature grades
| Austenitic High Temperature | EN | ASTM |
| 4948 | 1.4948 | 304H |
| 4878 | 1.4878 | 321 |
| 153 MA | 1.4818 | - |
| 4833 | 1.4833 | 309S |
| 4828 | 1.4833 | - |
| 253 MA | 1.4835 | - |
| 4845 | 1.4845 | 310S |
| 4841 | 1.4841 | 314 |
Ferritic high temperature grades
| Ferritic High Temperature | EN | ASTM |
| 4713 | 1.4713 | - |
| 4724 | 1.4724 | - |
| 4736 | 1.4736 | - |
| 4742 | 1.4742 | - |
| 4762 | 1.4762 | - |
Properties
Mechanical properties of austenitic high temperature steels
Austenitic high temperature steels are mainly optimised for oxidation and high temperature corrosion resistance. However, they also have good mechanical properties, in part due to their austenitic structure and in part to certain alloying elements we employ.
When utilising these steels in one’s design, minimum proof strength values are usually employed for constructions expected to endure temperatures up to around 550°C. Above this level mean creep strength values are used.
At elevated temperatures we often witness widely ranging fatigue service conditions. In most cases a component will be subjected to loads and temperatures that vary considerably which in turn can eventually lead to fatigue failure. There are two principle types of isothermal fatigue: High Cycle Fatigue (HCF), which is stress controlled with low amplitudes and Low Cycle Fatigue (LCF) strain controlled with broad amplitudes and a correspondingly shorter life. HCF is typically encountered in rotating or vibrating components whereas LCF is usually caused by larger transients during start-ups, shut downs and major changes in service conditions.
Pure thermal fatigue in a component is caused by thermal gradients and the corresponding differences in (Internally constrained) thermal expansion. The most complex form of fatigue is when the temperature and load vary simultaneously and this is known as Thermomechanical Fatigue (TMF).
Mechanical properties of high temperature ferritic steels
High temperature ferritic stainless steels have broadly the same mechanical properties as their austenitic counterparts at room temperature. However, when subjected to high temperatures (> 600°C), it is possible for the creep strength to drop to just a quarter of the value an austenitic heat resistant steel would show in the same environment. Consequently it is important that loads applied to components are taken into consideration to ensure correct dimensions and construction are specified
Weldability
Welding of austenitic high temperature grades
High temperature constructions are frequently exposed to thermal fatigue due to variations in temperature. For this reason it is very important to design the welded joint without notches. Furthermore it is important that welds have oxidation resistance and creep strength compatible with the parent material. Autogenous welding of thin material is possible if full penetration can be achieved. Fillet welds without full penetration should be avoided due to risk of thermal fatigue. Optimal design would call for welds to be located in low stress areas of the equipment being fabricated.
Austenitic grades 4948, 4878 and 153 MA™
The weldability of 4948, 4878 and 153 MA™ steel grades is similar to the Cr-Ni group due to ferritic solidification of the weld metal. When MAG welding is carried out with 21 10 N wire, a power source with pulse current may be necessary to obtain good weldability.
Austenitic grades 4833, 4828 and 253 MA®
If high temperature grade 253 MA® is to be employed at the highest temperature range, TIG, plasma or MAG processes should be used. Welding with MAG may require modern pulse equipment and the use of special shielding gases containing Ar, He and O2/CO2 to facilitate good arc stability and improved fluidity.
Austenitic grades 4845 and 4841
These fully austenitic steels are susceptible to hot cracking, and due to this the heat input should be limited to maximum 1.0 kJ/mm. For this reason SAW should be avoided. The use of filler and a basic flux/coating will reduce the risk of hot cracking. When welding heat resistant stainless steels to carbon steels, 23Cr 12Ni fillers can be used. A nickel-base filler may be a better alternative if there is a high risk of loss of strength in the HAZ of the carbon steel. The reason is that if carbon in the construction steel may diffuse into the low carbon weld metal, the HAZ in the carbon steel will lose strength. Repair welding of exposed and damaged high temperature equipment is easily performed with MMA. Before welding, it is important to remove all magnetic areas close to the weld joint since these may contain embrittling phases. Machining or grinding are suitable methods.
Welding of ferritic high temperature grades
This group of ferritic steels are mostly used in high temperature applications with sulphurous atmospheres and/or low tensile load. They have limited weldability and the HAZ will have a ferritic-martensitic microstructure. The main alloying element in high temperature ferritic stainless steels is chromium. Its positive effect on scaling resistance is enhanced by silicon and aluminium. The two lower alloyed grades are best suited for temperatures between 550°C and 850°C. The higher alloyed ones are used at temperatures up to 1150°C and show excellent resistance to reducing sulphur-containing environments and molten metals, e.g. Cu. The alloying with aluminium also gives precipitates that reduce the sensitivity to grain growth during welding. For this reason, the steels can be produced and welded in thickness above 10 mm.
Ferritic grades 4713, 4724, 4742 and 4762
With these grades the same precautions as for carbon steels are normally required. Preheating of the joint to 200-300°C is necessary for materials thicker than 3 mm and the interpass temperatures should be in the same range. Due to grain growth in HAZ, the heat input should be minimised. Gas shielded welding methods are preferred. Pure argon should be used as shielding gas. Matching filler material has detrimental effect on the ductility which is why austenitic welding consumables, e.g. 18 8 Mn, 23 12 or 25 20 are commonly used. If the weld will be exposed to a sulphurous environment, overlay welding with matching ferritic filler will be necessary
Corrosion Resistant
The resistance of a material to high-temperature corrosion is in many cases dependent on its ability to form a protective oxide layer. In a reducing atmosphere, when such a layer cannot be created (or maintained), the corrosion resistance of the material will be determined by the alloy content of the material.
Forms
You can get high temperature austenitic grades in a variety of forms:
- Coil and sheet
- Thin strip
- Pipes
- Quarto plate
- Long products
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